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Diastereoselective Coupling of Chiral Acetonide Trisubstituted Radicals with Alkenes
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https://doi.org/10.1002/chem.201601957Abstract
The stereochemical outcome of reactions of chiral nucleophilic trisubstituted acetonide radicals with electron-deficient alkenes is dictated by a delicate balance between destabilizing non-bonding interactions and stabilizing hydrogen-bonding between substituents on the α and β carbons.
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