Lawrence Berkeley National Laboratory

Direct lithium extraction (DLE) of brines after geothermal power production offers opportunities to produce environmentally benign “green” lithium; however, some environmental impact is inevitable. We examined solid waste production at geothermal power plants in southern California that are also locations for planned DLE facilities. Currently, the geothermal plants in this region produce approximately 79,800 metric tons (wet weight) per year of solid waste, which represents about 28 metric tons per GWh of net electricity production or approximately 500 mg solids per kg geothermal brine. Approximately 15% of this waste requires management as hazardous waste. Solids produced during power production represent about 0.2% of the total dissolved solids in the brine. Lithium production will require the removal of silica, iron, and other metals as part of the DLE process. Using a mass balance approach, we calculate that precipitation of silica and metals could produce up to an additional 6800 mg solids per kg brine. Calcium occurs at very high concentrations, and the amount of solids disposed in landfills will be dependent on the amount of calcium removed during lithium recovery. Our analysis shows that evaluation of brine chemistry in the context of the DLE process is useful for evaluating the potential solid waste impacts of producing lithium from brines.