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Ultrafast solvent-induced charge localization in Tris-(2,2'-Bipyridine) Ruthenium(II)
Abstract
Two distinct excited state processes are resolved intris-[2,2'-bipyridine] ruthenium(II). Time resolved anisotropy measurements reveal a solvent dependent depolarization indicative of charge localization. Transient absorption measurements resolve wavepacket motion on the excited state surface(s) independent of solvent.
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