UCLA

Lanthanide hexaborides (LnB₆ ) have disparate and often anomalous properties, from structurally homogeneous mixed valency, to superconductivity, spectral anomalies, and unexplained phase transitions. It is unclear how such a diversity of properties may arise in the solids of identical crystal structures and seemingly very similar electronic structures. Building on our previous model for SmB₆ (mixed valent, with a peak in specific heat, and pressure induced magnetic phase transitions), we present a unifying dynamic bonding model for LnB₆ that explains simultaneously EuB₆ (possessing an anomalous peak in specific heat at low T, magnetic phase transitions, and no mixed valency), YbB₆ (mixed valent topological insulator), and rather ordinary LaB₆ . We show that Ln can engage in covalent bonding with boron, and, in some members of the LnB₆ family, also easily access alternative bonding states through the electron-phonon coupling. The accessibility, relative energetics, and bonding nature of the states involved dictate the properties.