Lauretta (2005) produced sulfide in the laboratory by exposing canonical nebular metal analogs to H2S gas under temperatures and pressures relevant to the formation of the Solar System. The resulting reactions produced a suite of sulfides and nanophase materials not visible at the microprobe scale, but which we have now analyzed by TEM for comparison with interplanetary dust samples and comet Wild 2 samples returned by the Stardust mission. We find the unexpected result that disequilibrium formation favors pyrrhotite over troilite and also produces minority schreibersite, daubréelite, barringerite, taenite, oldhamite, and perryite at the metal-sulfide interface. TEM identification of nanophases and analysis of pyrrhotite superlattice reflections illuminate the formation pathway of disequilibrium sulfide. We discuss the conditions under which such disequilibrium can occur, and implications for formation of sulfide found in extraterrestrial materials.

The past decade has witnessed the development of layered-hydroxide-based self-supporting electrodes, but the low active mass ratio impedes its all-around energy-storage applications. Herein, the intrinsic limit of layered hydroxides is broken by engineering F-substituted β-Ni(OH)₂ (Ni-F-OH) plates with a sub-micrometer thickness (over 700 nm), producing a superhigh mass loading of 29.8 mg cm^-2 on the carbon substrate. Theoretical calculation and X-ray absorption spectroscopy analysis demonstrate that Ni-F-OH shares the β-Ni(OH)₂ -like structure with slightly tuned lattice parameters. More interestingly, the synergy modulation of NH₄ ⁺ and F^- is found to serve as the key enabler to tailor these sub-micrometer-thickness 2D plates thanks to the modification effects on the (001) plane surface energy and local OH^- concentration. Guided by this mechanism, the superstructures of bimetallic hydroxides and their derivatives are further developed, revealing they are a versatile family with great promise. The tailored ultrathick phosphide superstructure achieves a superhigh specific capacity of 7144 mC cm^-2 and a superior rate capability (79% at 50 mA cm^-2 ). This work highlights a multiscale understanding of how exceptional structure modulation happens in low-dimensional layered materials. The as-built unique methodology and mechanisms will boost the development of advanced materials to better meet future energy demands.