UC Berkeley

Two dimensional (2D) materials have found various applications because of their unique physical properties. For example, graphene has been used as the electron transparent membrane for liquid cell transmission electron microscopy (TEM) due to its high mechanical strength and flexibility, single-atom thickness, chemical inertness, etc. Here, we report using 2D MoS₂ as a functional substrate as well as the membrane window for liquid cell TEM, which is enabled by our facile and polymer-free MoS₂ transfer process. This provides the opportunity to investigate the growth of Pt nanocrystals on MoS₂ substrates, which elucidates the formation mechanisms of such heterostructured 2D materials. We find that Pt nanocrystals formed in MoS₂ liquid cells have a strong tendency to align their crystal lattice with that of MoS₂, suggesting a van der Waals epitaxial relationship. Importantly, we can study its impact on the kinetics of the nanocrystal formation. The development of MoS₂ liquid cells will allow further study of various liquid phenomena on MoS₂, and the polymer-free MoS₂ transfer process will be implemented in a wide range of applications.