- Asakura, Daisuke;
- Hosono, Eiji;
- Nanba, Yusuke;
- Zhou, Haoshen;
- Okabayashi, Jun;
- Ban, Chunmei;
- Glans, Per-Anders;
- Guo, Jinghua;
- Mizokawa, Takashi;
- Chen, Gang;
- Achkar, Andrew J;
- Hawthron, David G;
- Regier, Thomas Z;
- Wadati, Hiroki
We evaluate the utilities of fluorescence-yield (FY) modes in soft X-ray absorption spectroscopy (XAS) of several cathode materials for Li-ion batteries. In the case of total-FY (TFY) XAS for LiNi0.5Mn1.5O4, the line shape of the Mn L3-edge XAS was largely distorted by the self-absorption and saturation effects, while the distortions were less pronounced at the Ni L3 edge. The distortions were suppressed for the inverse-partial-FY (IPFY) spectra. We found that, in the cathode materials, the IPFY XAS is highly effective for the Cr, Mn, and Fe L edges and the TFY and PFY modes are useful enough for the Ni L edge which is far from the O K edge.