Covert and side channel attacks are an emerging class of dangerous cybersecurity attacks.These attacks exploit the sharing of resources between two different processes when theyexecute on the same system and share hardware or software resources. Applications are protectedfrom direct access to each other’s state by hardware and operating system protections but can useobservable delays when they use shared resources to communicate (covert channels) or spy oneach other (side channels). In this paper, we focus on a new type of covert and side channelattacks that exploits the Linux virtual file system (VFS). We start by showing how the syncfssystem call can lead to observable differences in timing, and how these differences can beexploited to build covert and side channel attacks. We target the file system wide disksynchronization mechanism in the syncfs system call and explore the time difference whenflushing the dirty pages in the page cache. The covert channel attack is built based on whetherthere are dirty pages that can be flushed. Besides that, we further explore the opportunity of sidechannel attack and construct a website fingerprinting attack and a video fingerprinting attack.

The addition of iodide (I^-) in the UV/sulfite system (UV/S) significantly accelerated the reductive degradation of perfluorosulfonates (PFSAs, C_nF_2n+1SO₃^-) and perfluorocarboxylates (PFCAs, C_nF_2n+1COO^-). Using the highly recalcitrant perfluorobutane sulfonate (C₄F₉SO₃^-) as a probe, we optimized the UV/sulfite + iodide system (UV/S + I) to degrade n = 1-7 PFCAs and n = 4, 6, 8 PFSAs. In general, the kinetics of per- and polyfluoroalkyl substance (PFAS) decay, defluorination, and transformation product formations in UV/S + I were up to three times faster than those in UV/S. Both systems achieve a similar maximum defluorination. The enhanced reaction rates and optimized photoreactor settings lowered the EE/O for PFCA degradation below 1.5 kW h m^-3. The relatively high quantum yield of e_aq^- from I^- made the availability of hydrated electrons (e_aq^-) in UV/S + I and UV/I two times greater than that in UV/S. Meanwhile, the rapid scavenging of reactive iodine species by SO₃^2- made the lifetime of e_aq^- in UV/S + I eight times longer than that in UV/I. The addition of I^- also substantially enhanced SO₃^2- utilization in treating concentrated PFAS. The optimized UV/S + I system achieved >99.7% removal of most PFSAs and PFCAs and >90% overall defluorination in a synthetic solution of concentrated PFAS mixtures and NaCl. We extended the discussion over molecular transformation mechanisms, development of PFAS degradation technologies, and the fate of iodine species.

Environmental pollution is escalating due to rapid global development that often prioritizes human needs over planetary health. Despite global efforts to mitigate legacy pollutants, the continuous introduction of new substances remains a major threat to both people and the planet. In response, global initiatives are focusing on risk assessment and regulation of emerging contaminants, as demonstrated by the ongoing efforts to establish the UNs Intergovernmental Science-Policy Panel on Chemicals, Waste, and Pollution Prevention. This review identifies the sources and impacts of emerging contaminants on planetary health, emphasizing the importance of adopting a One Health approach. Strategies for monitoring and addressing these pollutants are discussed, underscoring the need for robust and socially equitable environmental policies at both regional and international levels. Urgent actions are needed to transition toward sustainable pollution management practices to safeguard our planet for future generations.