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Open Access Publications from the University of California

Scholarly Works (4 results)

  • Article
LBL Publications (2014)
The first synthesis and structural characterization of actinide corroles is presented. Thorium(IV) and uranium(IV) macrocycles of Mes2(p-OMePh)corrole were synthesised and characterized by single-crystal X-ray diffraction, UV-Visible spectroscopy, variable-temperature 1H NMR, ESI mass spectrometry and cyclic voltammetry.
    Cover page: Actinide Corroles: Synthesis and Characterization of Thorium(IV) and Uranium(IV) bis(-chloride) Dimers
    • Article
    • Peer Reviewed
    UC Berkeley Previously Published Works (2020)
    A multicomponent reaction among dipyrranes, aryl-propargyl aldehydes, and p-chloranil leading to 10-(benzofuran-2-yl)corroles is described. p-Chloranil was identified as a crucial reagent playing a twofold role: an oxidant taking part in the formation of the corrole macrocycle and a component undergoing heteroannulation to the incipient 10-arylethynylcorrole. A series of corroles bearing persubstituted benzofuran-2-yl moieties have been synthesized, and their fundamental electronic properties have been studied via UV-vis absorption and fluorescence spectroscopies.
      Cover page: Access to Corrole-Appended Persubstituted Benzofurans by a Multicomponent Reaction: The Dual Role of p‑Chloranil
      • Article
      • Peer Reviewed
      UC Berkeley Previously Published Works (2014)
        Cover page: Corroles That “Click”: Modular Synthesis of Azido- and Propargyl-Functionalized Metallocorrole Complexes and Convergent Synthesis of a Bis-corrole Scaffold
        • Article
        • Peer Reviewed
        UC Lab Fees Research Program (LFRP) Funded Publications (2014)
          Cover page: Corroles That “Click”: Modular Synthesis of Azido- and Propargyl-Functionalized Metallocorrole Complexes and Convergent Synthesis of a Bis-corrole Scaffold
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