- Xiao, Qiangfeng;
- Gu, Meng;
- Yang, Hui;
- Li, Bing;
- Zhang, Cunman;
- Liu, Yang;
- Liu, Fang;
- Dai, Fang;
- Yang, Li;
- Liu, Zhongyi;
- Xiao, Xingcheng;
- Liu, Gao;
- Zhao, Peng;
- Zhang, Sulin;
- Wang, Chongmin;
- Lu, Yunfeng;
- Cai, Mei
Silicon has been identified as a highly promising anode for next-generation lithium-ion batteries (LIBs). The key challenge for Si anodes is large volume change during the lithiation/delithiation cycle that results in chemomechanical degradation and subsequent rapid capacity fading. Here we report a novel fabrication method for hierarchically porous Si nanospheres (hp-SiNSs), which consist of a porous shell and a hollow core. On charge/discharge cycling, the hp-SiNSs accommodate the volume change through reversible inward Li breathing with negligible particle-level outward expansion. Our mechanics analysis revealed that such inward expansion is enabled by the much stiffer lithiated layer than the unlithiated porous layer. LIBs assembled with the hp-SiNSs exhibit high capacity, high power and long cycle life, which is superior to the current commercial Si-based anode materials. The low-cost synthesis approach provides a new avenue for the rational design of hierarchically porous structures with unique materials properties.