We present CO J=4-3 line and 3 mm dust continuum observations of a 100 kpc-scale filamentary Ly{\alpha} nebula (SSA22 LAB18) at z=3.1 using the Atacama Large Millimeter/submillimeter Array (ALMA). We detected the CO J=4-3 line at a systemic z(CO)=3.093 {\pm} 0.001 at 11 {\sigma} from one of the ALMA continuum sources associated with the Ly{\alpha} filament. We estimated the CO J=4-3 luminosity of L'CO(4-3)=(2.3\pm0.2)x10^9 K km s^{-1} pc^2 for this CO source, which is one order of magnitude smaller than those of typical z>1 dusty star-forming galaxies (DSFGs) of similar far-infrared luminosity L(IR)~10^{12} Lsun. We derived a molecular gas mass of Mgas=(4.4^{+0.9}_{-0.6})x10^9 Msun and a star-formation rate of SFR=270\pm160 Msun yr^{-1}. We also estimated a gas depletion time of {\tau}(dep)=17\pm10 Myr, being shorter than those of typical DSFGs. It is suggested that this source is in a transition phase from DSFG to a gas-poor, early-type galaxy. From ALMA to Herschel multi-band dust continuum observations, we measured a dust emissivity index {\beta}=2.3\pm0.2, which is similar to those of local gas-poor, early-type galaxies. Such a high {\beta} can be reproduced by specific chemical compositions for interstellar dust at the submillimeter wavelengths from recent laboratory experiments. ALMA CO and multi-band dust continuum observations can constrain the evolutionary stage of high-redshift galaxies through {\tau}(dep) and {\beta}, and thus we can investigate dust chemical compositions even in the early Universe.

We have obtained three-dimensional maps of the universe in ∼200 × 200 × 80 comoving Mpc3 (cMpc3) volumes each at z = 5.7 and 6.6 based on a spectroscopic sample of 179 galaxies that achieves ⪆80% completeness down to the Lyα luminosity of, based on our Keck and Gemini observations and the literature. The maps reveal filamentary large-scale structures and two remarkable overdensities made out of at least 44 and 12 galaxies at z = 5.692 (z57OD) and z = 6.585 (z66OD), respectively, making z66OD the most distant overdensity spectroscopically confirmed to date, with >10 spectroscopically confirmed galaxies. We compare spatial distributions of submillimeter galaxies at z ≃ 4-6 with our z = 5.7 galaxies forming the large-scale structures, and detect a 99.97% signal of cross-correlation, indicative of a clear coincidence of dusty star-forming galaxy and dust-unobscured galaxy formation at this early epoch. The galaxies in z57OD and z66OD are actively forming stars with star-formation rates (SFRs) ⪆5 times higher than the main sequence, and particularly the SFR density in z57OD is 10 times higher than the cosmic average at the redshift (a.k.a. the Madau-Lilly plot). Comparisons with numerical simulations suggest that z57OD and z66OD are protoclusters that are progenitors of the present-day clusters with halo masses of ∼1014 M o˙