This dissertation undertakes a comprehensive exploration of computational methods for studying and optimizing plasma processes, focusing specifically on the behavior and characteristics of atmospheric plasmas under various ignition waveforms. Leveraging somaFOAM, an in-house plasma solver based on OpenFOAM, this research delves into the effects of different voltage profiles—including sinusoidal, unipolar, bipolar, and sinusoidal damped waveforms—on plasma stability and efficiency. While atmospheric plasmas provide potential novel applications in medical, surface treatment, water purification, and decontamination of surfaces, the main limitation is the inherent instability of atmospheric plasma due to the high breakdown voltage. Furthermore, its traditional mode of operation, which consists of filamentary discharges, can be counterproductive to surface treatment as the filaments current are discretized, now allowing for fine control of the system when the sensitivity of the surface needs to be considered, alongside the nonuniform mode of operation. As such, atmospheric pressure glow discharges, operating in the radio frequency regime, allow for modular control of the plasma intensity while allowing the surface to be treated uniformly. Further study is of interest to supplant and replace depending on the application filamentary discharges. However, a systematic understanding of the controlling parameters within the plasma is required to have a stable glow discharge, as the ignition of an atmospheric glow discharge is inherently difficult due to the high power required to operate at atmospheric pressure. As such, it is interesting to study modes of control to ignite a stable plasma while simultaneously maximizing its reactivity, as these properties are inverse to each other.
As such, the first project aims to consider control of the input parameters by utilizing different ignition waveforms at the same cycled-averaged power to study the effects of utilizing different waveforms on plasma stability and reactivity. However, as the feedstock gases also affect the characterization of the waveforms, two feedstock gases, argon and helium, are utilized to establish independence or dependence on the feedstock gas while at the same time studying the benefits of each feedstock gas, helium provides ease of operation and characterization, argon has been touted as a low-cost alternative which also promises ease of operation in comparison to other feedstock gas. Analysis is provided to determine whether the plasma operates in the α or γ mode of operation. However, further research is required, such as determining the criticality of the waveforms utilized to operate the plasma while at the same time investigating the effects of dielectric barrier discharges to maximize reactivity within the system, as previous research in the kilohertz regime seems to indicate that dielectrics can stabilize the plasma operation.
The second project further investigates argon plasma as research also considers the potential for scalability of the plasma, for which argon provides an opportunity. α-γ relationship between the voltage and current, the relationship between the γ mode of operation and a plasma dominated by secondary electron emissions followed by the study of the electron profiles as a relationship of stability, the relationship between the bulk voltage and input voltage for the pulsed waveforms for power coupling are studied for bare electrodes in order to provide a comprehensive picture of the plasma characterization, allowing for a deeper study of the plasma physics compared to the first project which one touched to a surface level as the interest was to determine the effects of the waveform coupled with the feedstock gas. At the same time, the addition of dielectric elements is considered within the dielectric gap to characterize the addition of such elements into the plasma and whenever such a strategy to maximize reactivity and stability is feasible. The third project, inspired upon the numerical downtime of utilizing modeling techniques in the second project, intends to use dynamic mode decomposition as a data-driven method to obtain a prediction that is adequate for purposes of analysis and characterization of the plasma without the computational downtime, utilizing a domain of parametrized solutions to train the model. Three cases are evaluated, with the first case at the boundary of the solution domain, the second case within the domain of the solution, and the third case partially outside the domain of the solution to evaluate edge cases and cases within the domain of the solution to determine the strength and weaknesses of the prediction, to be able to utilize data-driven techniques with existing databases to be able to characterize the plasma without the computational burden encountered with modeling techniques, allowing for just-in-time data results, improving efficiency.
The different projects presented here aim to comprehensively describe atmospheric plasmas and their characterization under different feedstock gases and input waveforms in order to propose a new way to maximize stability and reactivity simultaneously, utilizing a control approach to achieve this. At the same time, as parametrization techniques are computationally expensive, a data-driven technique could be seen as another tool to minimize computational downtime while obtaining results that can be utilized to understand the plasma characterization, allowing for a more efficient control mode of the plasma.