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Scholarly Works (2 results)

  • Article
  • Peer Reviewed
UC Irvine Previously Published Works (2010)
We have developed a detailed chemical scheme for the degradation of the short-lived source gases bromoform (CHBr(3)) and dibromomethane (CH(2)Br(2)) and implemented it in the TOMCAT/SLIMCAT three-dimensional (3-D) chemical transport model (CTM). The CTM has been used to predict the distribution of the two source gases (SGs) and 11 of their organic product gases (PGs). These first global calculations of the organic PGs show that their abundance is small. The longest lived organic PGs are CBr(2)O and CHBrO, but their peak tropospheric abundance relative to the surface volume mixing ratio (vmr) of the SGs is less than 5%. We calculate their mean local tropospheric lifetimes in the tropics to be similar to 7 and similar to 2 days (due to photolysis), respectively. Therefore, the assumption in previous modelling studies that SG degradation leads immediately to inorganic bromine seems reasonable. We have compared observed tropical SG profiles from a number of aircraft campaigns with various model experiments. In the tropical tropopause layer (TTL) we find that the CTM run using p levels (TOMCAT) and vertical winds from analysed divergence overestimates the abundance of CH(2)Br(2), and to a lesser extent CHBr(3), although the data is sparse and comparisons are not conclusive. Better agreement in the TTL is obtained in the sensitivity run using theta levels (SLIMCAT) and vertical motion from diabatic heating rates. Trajectory estimates of residence times in the two model versions show slower vertical transport in the SLIMCAT theta-level version. In the p-level model even when we switch off convection we still find significant amounts of the SGs considered may reach the cold point tropopause; the stratospheric source gas injection (SGI) is only reduced by similar to 16% for CHBr(3) and similar to 2% for CH(2)Br(2) without convection. Overall, the relative importance of the SG pathway and the PG pathway for transport of bromine to the stratospheric overworld (theta > 380 K) has been assessed. Assuming a 10-day washout lifetime of Br(y) in TOMCAT, we find the delivery of total Br from CHBr(3) to be 0.72 pptv with similar to 53% of this coming from SGI. Similary, for CH(2)Br(2) we find a total Br value of 1.69 pptv with similar to 94% coming from SGI. We infer that these species contribute similar to 2.4 pptv of inorganic bromine to the lower stratosphere with SGI being the dominant pathway. Slower transport to and through the TTL would decrease this estimate.
    Cover page: Bromoform and dibromomethane in the tropics: a 3-D model study of chemistry and transportCreative Commons 'BY' version 4.0 license
    • Article
    • Peer Reviewed
    Faculty Publications (2005)

    Accurate and reliable predictions and an understanding of future changes in the stratosphere are major aspects of the subject of climate change. Simulating the interaction between chemistry and climate is of particular importance, because continued increases in greenhouse gases and a slow decrease in halogen loading are expected. These both influence the abundance of stratospheric ozone. In recent years a number of coupled chemistry–climate models (CCMs) with different levels of complexity have been developed. They produce a wide range of results concerning the timing and extent of ozone-layer recovery. Interest in reducing this range has created a need to address how the main dynamical, chemical, and physical processes that determine the long-term behavior of ozone are represented in the models and to validate these model processes through comparisons with observations and other models. A set of core validation processes structured around four major topics (transport, dynamics, radiation, and stratospheric chemistry and microphysics) has been developed. Each process is associated with one or more model diagnostics and with relevant datasets that can be used for validation. This approach provides a coherent framework for validating CCMs and can be used as a basis for future assessments. Similar efforts may benefit other modeling communities with a focus on earth science research as their models increase in complexity.

      Cover page: A Strategy for Process-Oriented Validation of Coupled Chemistry-Climate ModelsCreative Commons 'BY' version 4.0 license
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