Abstract. Commonly, three mechanisms of firn air transport are distinguished: molecular diffusion, advection, and near-surface convective mixing. Here we identify and describe a fourth mechanism, namely dispersion driven by synoptic-scale surface pressure variability (or barometric pumping). We use published gas chromatography experiments on firn samples to derive the along-flow dispersivity of firn, and combine this dispersivity with a dynamical air pressure propagation model forced by surface air pressure time series to estimate the magnitude of dispersive mixing in the firn. We show that dispersion dominates mixing within the firn lock-in zone. Trace gas concentrations measured in firn air samples from various polar sites confirm that dispersive mixing occurs. Including dispersive mixing in a firn air transport model suggests that our theoretical estimates have the correct order of magnitude, yet may overestimate the true dispersion. We further show that strong barometric pumping, such as at the Law Dome site, may reduce the gravitational enrichment of δ15N–N2 and other tracers below gravitational equilibrium, questioning the traditional definition of the lock-in depth as the depth where δ15N enrichment ceases. Last, we propose that 86Kr excess may act as a proxy for past synoptic activity (or paleo-storminess) at the site.

Abstract. Ancient air trapped in ice core bubbles has been paramount to developing our understanding of past climate and atmospheric composition. Before air bubbles become isolated in ice, the atmospheric signal is altered in the firn column by transport processes such as advection and diffusion. However, the influence of low-permeability layers and barometric pumping (driven by surface pressure variability) on firn air transport is not well understood and is not readily captured in conventional one-dimensional (1-D) firn air models. Here we present a two-dimensional (2-D) trace gas advection–diffusion–dispersion model that accounts for discontinuous horizontal layers of reduced permeability. We find that layering or barometric pumping individually yields too small a reduction in gravitational settling to match observations. In contrast, when both effects are active, the model's gravitational fractionation is suppressed as observed. Layering focuses airflows in certain regions in the 2-D model, which acts to amplify the dispersive mixing resulting from barometric pumping. Hence, the representation of both factors is needed to obtain a realistic emergence of the lock-in zone. In contrast to expectations, we find that the addition of barometric pumping in the layered 2-D model does not substantially change the differential kinetic fractionation of fast- and slow-diffusing trace gases. Like 1-D models, the 2-D model substantially underestimates the amount of differential kinetic fractionation seen in actual observations, suggesting that further subgrid-scale processes may be missing in the current generation of firn air transport models. However, we find robust scaling relationships between kinetic isotope fractionation of different noble gas isotope and elemental ratios. These relationships may be used to correct for kinetic fractionation in future high-precision ice core studies and can amount to a bias of up to 0.45 °C in noble-gas-based mean ocean temperature reconstructions at WAIS Divide, Antarctica.

Abstract. Ancient air trapped in ice core bubbles has been paramount to developing our understanding of past climate and atmospheric composition. Before air bubbles become isolated in ice, the atmospheric signal is altered in the firn column by transport processes such as advection and diffusion. However, the influence of impermeable layers and barometric pumping (driven by surface pressure variability) on firn air transport is not well understood and cannot be captured in conventional 1-dimensional firn air models. Here we present a 2-dimensional (2D) trace gas advection-diffusion-dispersion model that accounts for discontinuous horizontal layers of reduced permeability. We find that layering and barometric pumping individually yield too small a reduction in gravitational settling to match observations. In contrast, a combination of both effects more strongly suppresses gravitational fractionation. Layering locally focuses airflows in the 2D model and thus amplifies the dispersive mixing resulting from barometric pumping. Hence, the representation of both factors is needed to obtain a more natural emergence of the lock-in zone. Moreover, we find that barometric pumping in the layered 2D model does not substantially change the differential kinetic fractionation of fast and slow diffusing trace gases, which is observed in nature. This suggests that further subgrid-scale physics may be missing in the current generation of firn air transport models. However, we find robust scaling relationships between kinetic isotope fractionation of different noble gas isotope and elemental ratios. These relationships may be used to correct for kinetic fractionation in future high precision ice core studies.

Abstract. Gas isotope thermometry using the isotopes of molecular nitrogen and argon has been used extensively to reconstruct past surface temperature change from Greenland ice cores. The gas isotope ratios δ15N and δ40Ar in the ice core are each set by the amount of gravitational and thermal fractionation in the firn. The gravitational component of fractionation is proportional to the firn thickness, and the thermal component is proportional to the temperature difference between the top and bottom of the firn column, which can be related to surface temperature change. Compared to Greenland, Antarctic climate change is typically more gradual and smaller in magnitude, which results in smaller thermal fractionation signals that are harder to detect. This has hampered application of gas isotope thermometry to Antarctic ice cores. Here, we present an analytical method for measuring δ15N and δ40Ar with a precision of 0.002 ‰ per atomic mass unit, a two-fold improvement on previous work. This allows us to reconstruct changes in firn thickness and temperature difference at the South Pole between 30 and 5 kyr BP. We find that variability in firn thickness is controlled in part by changes in snow accumulation rate, which is, in turn, influenced strongly by the along-flowline topography upstream of the ice core site. Variability in our firn temperature difference record cannot be explained by annual-mean processes. We therefore propose that the ice core gas isotopes contain a seasonal bias due to rectification of seasonal signals in the upper firn. The strength of the rectification also appears to be linked to fluctuations in the upstream topography. As further evidence for the existence of rectification, we present new data from the Dome Fuji ice core that are also consistent with a seasonal bias throughout the Holocene. Our findings have important implications for the interpretation of ice core gas records. For example, we show that the effects of upstream topography on ice core records can be significant at flank sites like the South Pole – they are responsible for some of the largest signals in our record. Presumably upstream signals impact other flank-flow ice cores such as EDML, Vostok, and EGRIP similarly. Additionally, future work is required to confirm the existence of seasonal rectification in polar firn, to determine how spatially and temporally widespread rectifier effects are, and to incorporate the relevant physics into firn air models.

Abstract. Marine sediments, speleothems, paleo-lake elevations, and ice core methane and δ18O of O2 (δ18Oatm) records provide ample evidence for repeated abrupt meridional shifts in tropical rainfall belts throughout the last glacial cycle. To improve understanding of the impact of abrupt events on the global terrestrial biosphere, we present composite records of δ18Oatm and inferred changes in fractionation by the global terrestrial biosphere (ΔεLAND) from discrete gas measurements in the WAIS Divide (WD) and Siple Dome (SD) Antarctic ice cores. On the common WD timescale, it is evident that maxima in ΔεLAND are synchronous with or shortly follow small-amplitude WD CH4 peaks that occur within Heinrich stadials 1, 2, 4, and 5 – periods of low atmospheric CH4 concentrations. These local CH4 maxima have been suggested as markers of abrupt climate responses to Heinrich events. Based on our analysis of the modern seasonal cycle of gross primary productivity (GPP)-weighted δ18O of terrestrial precipitation (the source water for atmospheric O2 production), we propose a simple mechanism by which ΔεLAND tracks the centroid latitude of terrestrial oxygen production. As intense rainfall and oxygen production migrate northward, ΔεLAND should decrease due to the underlying meridional gradient in rainfall δ18O. A southward shift should increase ΔεLAND. Monsoon intensity also influences δ18O of precipitation, and although we cannot determine the relative contributions of the two mechanisms, both act in the same direction. Therefore, we suggest that abrupt increases in ΔεLAND unambiguously imply a southward shift of tropical rainfall. The exact magnitude of this shift, however, remains under-constrained by ΔεLAND.

Abstract. Deglaciations are characterized by relatively fast and near-synchronous changes in ice sheet volume, ocean temperature, and atmospheric greenhouse gas concentrations, but glacial inceptions occur more gradually. Understanding the evolution of ice sheet, ocean, and atmospheric conditions from interglacial to glacial maximum provides important insight into the interplay of these components of our climate system. Using noble gas measurements in ancient ice samples, we reconstruct mean ocean temperature (MOT) from 74 to 59.5 ka BP, covering the Marine Isotope Stage (MIS) 5-4 boundary, MIS 4, and part of the MIS 4-3 transition. Comparing this MOT reconstruction to previously published MOT reconstructions from the last glacial cycle, we find that the majority of interglacial-glacial ocean cooling occurred across MIS 5, and MOT reached full glacial levels by MIS 4 (−2.7 ± 0.3 °C relative to the Holocene). Comparing MOT to contemporaneous records of CO2 and benthic 𝛿18O, we find that ocean cooling and the solubility pump can explain most of the CO2 drawdown and increase in 𝛿18O across MIS 5. The timing of ocean warming and cooling in our record indicates that millennial scale climate variability plays a crucial role in setting mean ocean temperature during this interval, as seen during other periods, such as the last deglaciation.

Abrupt climate changes during the last deglaciation have been well preserved in proxy records across the globe. However, one long-standing puzzle is the apparent absence of the onset of the Heinrich Stadial 1 (HS1) cold event around 18 ka in Greenland ice core oxygen isotope δ18O records, inconsistent with other proxies. Here, combining proxy records with an isotope-enabled transient deglacial simulation, we propose that a substantial HS1 cooling onset did indeed occur over the Arctic in winter. However, this cooling signal in the depleted oxygen isotopic composition is completely compensated by the enrichment because of the loss of winter precipitation in response to sea ice expansion associated with AMOC slowdown during extreme glacial climate. In contrast, the Arctic summer warmed during HS1 and YD because of increased insolation and greenhouse gases, consistent with snowline reconstructions. Our work suggests that Greenland δ18O may substantially underestimate temperature variability during cold glacial conditions.

Abstract. Deglaciations are characterized by relatively fast and near-synchronous changes in ice sheet volume, ocean temperature, and atmospheric greenhouse gas concentrations, but glacial inception occurs more gradually. Understanding the evolution of ice sheet, ocean, and atmosphere conditions from interglacial to glacial maximum provides insight into the interplay of these components of the climate system. Using noble gas measurements in ancient ice samples, we reconstruct mean ocean temperature (MOT) from 74 to 59.7 ka, covering the Marine Isotope Stage (MIS) 5a–4 boundary, MIS 4, and part of the MIS 4–3 transition. Comparing this MOT reconstruction to previously published MOT reconstructions from the last and penultimate deglaciation, we find that the majority of the last interglacial–glacial ocean cooling must have occurred within MIS 5. MOT reached equally cold conditions in MIS 4 as in MIS 2 (−2.7 ± 0.3 ∘C relative to the Holocene, −0.1 ± 0.3 ∘C relative to MIS 2). Using a carbon cycle model to quantify the CO2 solubility pump, we show that ocean cooling can explain most of the CO2 drawdown (32 ± 4 of 40 ppm) across MIS 5. Comparing MOT to contemporaneous records of benthic δ18O, we find that ocean cooling can also explain the majority of the δ18O increase across MIS 5 (0.7 ‰ of 1.3 ‰). The timing of ocean warming and cooling in the record and the comparison to coeval Antarctic isotope data suggest an intimate link between ocean heat content, Southern Hemisphere high-latitude climate, and ocean circulation on orbital and millennial timescales.

The most recent glacial to interglacial transition constitutes a remarkable natural experiment for learning how Earth's climate responds to various forcings, including a rise in atmospheric CO₂ This transition has left a direct thermal remnant in the polar ice sheets, where the exceptional purity and continual accumulation of ice permit analyses not possible in other settings. For Antarctica, the deglacial warming has previously been constrained only by the water isotopic composition in ice cores, without an absolute thermometric assessment of the isotopes' sensitivity to temperature. To overcome this limitation, we measured temperatures in a deep borehole and analyzed them together with ice-core data to reconstruct the surface temperature history of West Antarctica. The deglacial warming was [Formula: see text]C, approximately two to three times the global average, in agreement with theoretical expectations for Antarctic amplification of planetary temperature changes. Consistent with evidence from glacier retreat in Southern Hemisphere mountain ranges, the Antarctic warming was mostly completed by 15 kyBP, several millennia earlier than in the Northern Hemisphere. These results constrain the role of variable oceanic heat transport between hemispheres during deglaciation and quantitatively bound the direct influence of global climate forcings on Antarctic temperature. Although climate models perform well on average in this context, some recent syntheses of deglacial climate history have underestimated Antarctic warming and the models with lowest sensitivity can be discounted.