- Sidhik, Siraj;
- Metcalf, Isaac;
- Li, Wenbin;
- Kodalle, Tim;
- Dolan, Connor J;
- Khalili, Mohammad;
- Hou, Jin;
- Mandani, Faiz;
- Torma, Andrew;
- Zhang, Hao;
- Garai, Rabindranath;
- Persaud, Jessica;
- Marciel, Amanda;
- Muro Puente, Itzel Alejandra;
- Reddy, GN Manjunatha;
- Balvanz, Adam;
- Alam, Muhammad A;
- Katan, Claudine;
- Tsai, Esther;
- Ginger, David;
- Fenning, David P;
- Kanatzidis, Mercouri G;
- Sutter-Fella, Carolin M;
- Even, Jacky;
- Mohite, Aditya D
We present a design strategy for fabricating ultrastable phase-pure films of formamidinium lead iodide (FAPbI3) by lattice templating using specific two-dimensional (2D) perovskites with FA as the cage cation. When a pure FAPbI3 precursor solution is brought in contact with the 2D perovskite, the black phase forms preferentially at 100°C, much lower than the standard FAPbI3 annealing temperature of 150°C. X-ray diffraction and optical spectroscopy suggest that the resulting FAPbI3 film compresses slightly to acquire the (011) interplanar distances of the 2D perovskite seed. The 2D-templated bulk FAPbI3 films exhibited an efficiency of 24.1% in a p-i-n architecture with 0.5-square centimeter active area and an exceptional durability, retaining 97% of their initial efficiency after 1000 hours under 85°C and maximum power point tracking.